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Bond Enthalpies

Bond Enthalpies

Define the term average bond enthalpy

 Average Bond Enthalpy – The amount of energy required to break one mole of bonds in the gaseous state averaged across a range of compounds containing that bond.

For example, in determining the bond enthalpy of C-H:

Explain, in terms of average bond enthalpies, why some reactions are exothermic and others are endothermic

Bond breaking

This is an endothermic process, as energy is absorbed to break the bonds between the atoms.

Bond making

This is an exothermic process, as energy is released when the bonds form between the atoms.

If more energy is released in the formation of bonds in the products that was required to break the bonds of the reactants, then the reaction is exothermic. If more energy is required to break the bonds of the reactants than is released in the formation of bonds in the products, then the reaction is endothermic

The bond enthalpies are used to calculate the enthalpies of the reaction. This is only approximate because only average bond enthalpies are used

is the sum of the terms

D is the bond enthalpy per mole of bonds

 

For example:

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